Reversible Polarographic Reduction of Niobium
نویسندگان
چکیده
منابع مشابه
POLAROGRAPHIC AND POTENTIOSTATIC REDUCTION OF CARBODIIMIDES: A MECHANISTIC STUDY
The polarographic reduction of aromatic carbodiimides in anhydrous aprotic solvents goes through a carbene intermediate by a diffusion controlled process in two one-electron steps. The first step is the rate-determining step and converts the carbodiirnide to a radical anion (6) that reduces further by a fast one-electron step to a carbene dianion intermediate (7). This abstracts an oxygen, ...
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The polarographic wave observed for acetonitrile solutions of benzoic acid is due to reduction of the acid proton: the apparent diffusion current constant for the wave increases with concentration of benzoic acid as expected for the reduction of the acidic proton of a slightly dissociated acid. No wave was observed for ethyl benzoate. The situation in respect to the electrochemical reduction of...
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ژورنال
عنوان ژورنال: Nature
سال: 1955
ISSN: 0028-0836,1476-4687
DOI: 10.1038/175477a0